Jul 31, 2007
Final CSB Report on Synthron Explosion Finds Inadequate Safety Controls for Chemical Reaction Hazards
Charlotte, NC, July 31, 2007 - In a final report released today on last year's fatal explosion at the Synthron chemical manufacturing facility in Morganton, North Carolina, the U.S. Chemical Safety Board (CSB) concluded that the company's management of reactive chemical hazards was inadequate and that the facility was unprepared for a chemical process emergency. The CSB also found that ineffective corporate oversight by French parent company Protex International contributed to the likelihood and severity of the accident.
The explosion occurred on January 31, 2006, as the result of a runaway chemical reaction in a 1500-gallon process vessel inside the Synthron production building. One worker was fatally burned and fourteen others were injured, two seriously. The blast destroyed the facility and broke windows up to one-third of a mile away. Two churches and a home were damaged and were later condemned. Synthron filed for bankruptcy following the accident, and the facility has not been rebuilt.
The CSB released a two-minute computer-animated video depicting the sequence of events that led to the Synthron explosion. This computer animation is part of a new 20-minute CSB safety video on reactive chemical hazards, which was also released today. The video will be distributed worldwide in an effort to draw increased attention to the dangers from uncontrolled chemical reactions.
"The accident at Synthron emphasizes the need for effective corporate oversight, emergency planning, and reactive chemical process training and safeguards," said Board Member John S. Bresland. "If these measures had been in place, this accident could have been prevented."
Synthron manufactured acrylic polymers for use as paint and coating additives. The polymers were typically produced inside a batch reactor by chemically reacting a blend of acrylic monomers in a mixture of flammable solvents. The polymerization reaction produced significant heat, which was removed by condensing the solvent vapor in an overhead, water-cooled condenser. The cooled, condensed solvent then flowed back into the reactor, keeping the temperature and the reaction under control.
The accident occurred when plant managers attempted to fulfill an order for acrylic polymer that exceeded the normal batch size for this product. Instead of making two smaller batches to fill the order, managers decided to make a single, larger batch. Managers decided to add all the extra acrylic monomer during the first stage of the reaction process, which was a critical mistake. Subsequent laboratory testing by the CSB showed that increasing the batch size in this manner raised the maximum heat output from the reaction by a factor of at least 2.3. The heat output exceeded the cooling capacity of the condenser, and the reaction accelerated out of control or "ran away."
After initiating the reaction on January 31, 2006, operators observed solvent vapor leaking from a hatchway on top of the reactor as the process overheated and pressure built up inside the reactor. Operators fled the production building and gathered just outside a doorway. A flammable vapor cloud formed inside the building, and a short time later it ignited and exploded, destroying the production facility and fatally burning a maintenance supervisor who had remained inside. Personnel who gathered just outside the building were among the injured.
CSB Lead Investigator Jim Lay said, "Synthron had apparently never documented the actual capacity of the cooling equipment, which was essential to keeping reactions from running out of control. The CSB found no evidence that the company had ever cleaned or inspected the cooling water side of the condenser on the reactor for 30 years." The CSB later found that this surface was fouled with scale, rust, and sediment which likely degraded the cooling capability of the condenser by at least 25 percent.
The CSB estimated that the flammable release occurred when the reactor reached a pressure of 23 pounds per square inch gauge (psig), which was well below the reactor's maximum working pressure of 75 psig. Further, Synthron had a longstanding practice of improperly securing the reactor hatch, using only four of the 18 metal clamps recommended by the manufacturer. Once the condenser cooling capacity was exceeded during the runaway reaction, the failure to fully clamp down the hatchway compromised the performance of the hatchway gasket, which allowed flammable solvent vapors to be released into the building.
The CSB investigation determined that Synthron had gathered only minimal safety information on its polymer-producing processes, and personnel, including the managers, were poorly prepared to recognize the dangers from an uncontrolled chemical reaction.
"We found that most of the management and operations personnel at Synthron had been on the job for less than a year - in some cases for only weeks or months," Mr. Lay stated. "The plant manager, superintendent, vice president, shift operators, and chemist all lacked experience in producing polymers."
The CSB found that Synthron had not performed a systematic safety review of the reactor, also known as a process hazard analysis. The facility also failed to install safeguards to automatically detect, prevent, or mitigate a runaway reaction.
The CSB also concluded that Synthron was not prepared for an emergency. Operating procedures did not instruct employees on what to do in the event of a chemical release or loss of chemical reactor control. Evacuation drills had not been conducted, and the facility was not equipped with an emergency alarm system. Investigators concluded there was adequate time available to have evacuated all personnel to a safe location after vapor escaped from the reactor hatchway. Such an evacuation would likely have prevented the death and injuries.
Synthron LLC was owned by a French company, Protex International, which has operations in Europe, Asia, North America, and South America. Protex has chemical facilities in Massachusetts, New Jersey, and Florida. The investigation found that Protex had testing equipment at its European facilities to measure chemical reaction hazards, but did not use this equipment to determine the safety of Synthron's processes or provide adequate technical support to Synthron.
The Board recommended that Protex International establish a program to follow good industry safety practices for managing reactive hazards at all its remaining U.S. facilities.
Mr. Bresland said, "When there is a possibility of a catastrophic process failure, such as a runaway chemical reaction, companies should always have multiple independent safeguards in place. Some examples include high pressure alarms, automatic emergency cooling systems, or automatic systems to empty the reactor contents to a safe location."
The CSB is an independent federal agency charged with investigating industrial chemical accidents. The agency's board members are appointed by the president and confirmed by the Senate. CSB investigations look into all aspects of chemical accidents, including physical causes such as equipment failure as well as inadequacies in regulations, industry standards, and safety management practices.
The Board does not issue citations or fines but does make safety recommendations to plants, industry organizations, labor groups, and regulatory agencies such as OSHA and EPA. Visit our website, www.csb.gov.
For more information, contact CSB Director of Public Affairs Dr. Daniel Horowitz (202) 441-6074 cell or Public Affairs Specialist Jennifer Jones at (202) 577-8448 cell.